北京林业大学学报2013,Vol.35Issue(4):118-122,5.
阻燃木粉-聚丙烯复合材料的热解特性及热解动力学研究
Pyrolysis characteristics and pyrolysis kinetics analysis of flame retarded wood flour-PP composites
摘要
Abstract
In order to research the pyrolysis characteristics of flame retarded wood flour(WF)-PP composites,thermogravimetric study of flame retarded wood-plastic composites using APP and M-APP was carried out using thermogravimetric analyzer (TGA) with N2 atmosphere at different heating rates.The pyrolysis kinetic equation was found,and the activation energy of pyrolysis process was obtained by TG spectra.The results showed that the initial decomposition temperature of WF-PP composite added with M-APP decreased,and the carbon residue was improved.The maximum decomposition temperature with WF decreased from 344.8 to 334.1 ℃,the maximum decomposition temperature with PP was improved from 518.5 to 525.6 ℃,and the carbon residue was increased from 19.4% to 21.7%.Then the activation energy with added M-APP was lower than that of added APP,so flame retardant effect of M-APP is better than APP for wood flour-PP composites.关键词
阻燃/木塑复合材料/热解特性/热解动力学Key words
flame retarded/ wood-plastic composites/ pyrolysis characteristics/ pyrolysis kinetics分类
农业科技引用本文复制引用
白钢,周林,李丽萍..阻燃木粉-聚丙烯复合材料的热解特性及热解动力学研究[J].北京林业大学学报,2013,35(4):118-122,5.基金项目
中央高校基本科研业务费(DL11CB03)、黑龙江省教育厅科学技术研究项目(11553032). (DL11CB03)