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复合球形LiFePO4/C的合成与电化学性能

陈星 刘开宇 李艳 吕美玉

电池2013,Vol.43Issue(3):136-138,3.
电池2013,Vol.43Issue(3):136-138,3.

复合球形LiFePO4/C的合成与电化学性能

Synthesis and electrochemical performance of ball-in-ball structure LiFePO4/C

陈星 1刘开宇 1李艳 1吕美玉1

作者信息

  • 1. 中南大学化学化工学院,湖南长沙410083
  • 折叠

摘要

Abstract

LiFePO4/C was synthesized by hydrothermal synthesis method using P123 (EO20PO70EO20)as template.The structure and morphology of the material were analyzed by XRD and SEM tests.Electrochemical performance of the material was studied by galvanostatic charge-discharge and cyclic voltammetry tests.The sample was pure phase LiFePO4 and had a structure of ball-in-ball When charged-discharged in 2.7 ~4.2 V,the 0.1 C and 10.0 C specific discharge capacity was 159 mAh/g and 93 mAh/g,respectively.When cycled in the order of0.1 C,0.5 C,1.0 C,2.0 C,10.0 C and 0.1 C for20 cycles in each current,it had no evident capacity fading after 120 cycles.

关键词

磷酸铁锂(LiFePO4)/P123/复合球形/电化学性能

Key words

lithium iron phosphate(LiFePO4) / P123 / ball-in-ball/ electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

陈星,刘开宇,李艳,吕美玉..复合球形LiFePO4/C的合成与电化学性能[J].电池,2013,43(3):136-138,3.

基金项目

国家自然科学基金(21071153) (21071153)

电池

OA北大核心CSCDCSTPCD

1001-1579

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