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P(PEGA-HAM)/PEG与PP共混蓄热调温纤维的制备及其性能

张鸿 刘辉 杨淑瑞 郭静 宫玉梅

大连工业大学学报2013,Vol.32Issue(3):194-198,5.
大连工业大学学报2013,Vol.32Issue(3):194-198,5.

P(PEGA-HAM)/PEG与PP共混蓄热调温纤维的制备及其性能

Preparation and characterization of thermo-regulating fiber of blend of P(PEGA-HAM)/PEG and PP

张鸿 1刘辉 1杨淑瑞 1郭静 1宫玉梅1

作者信息

  • 1. 大连工业大学纺织与材料工程学院,辽宁大连 116034
  • 折叠

摘要

Abstract

The different phase change materials content of thermo-regulating fiber was prepared through the melt spinning process.The chemical structure of the solid-solid phase particle and the chemical composition of ternary blend system were determined by IR analysis.The heat storage fiber thermal property,mechanical property and appearance shape was characterized by DSC,fiber tensile strength tester and SEM.The ternary blending system crystallization properties and rheological properties was characterized by XRD and capillary rheological meter.When P(PEGA-HAM)/PEG content was 12%,and PP-g-PEGA content was 3%,the tempering fiber phase transition enthalpy was 12.17 J/g,and fracture strength was 4.86 cN/dtex,the fiber surface was smooth and complete.The PP matrix of α crystal formation was destroyed with the P(PEGA-HAM)/PEG content increasing,leading to the reduction in the crystallinity of PP.The shear viscosity of ternary blend system showed first reducing then increasing in flow behavior when increased P(PEGA-HAM)/PEG solid-solid phase change particle,and shear viscosity was reduced with the rising temperature.

关键词

蓄热调温纤维/熔纺/聚乙二醇/固-固相变粒子

Key words

thermo-regulating fiber/ melt spinning/ polyethylene/ solid-solid phase change particle

分类

轻工纺织

引用本文复制引用

张鸿,刘辉,杨淑瑞,郭静,宫玉梅..P(PEGA-HAM)/PEG与PP共混蓄热调温纤维的制备及其性能[J].大连工业大学学报,2013,32(3):194-198,5.

基金项目

大连市科技基金项目(2010J21DW014). (2010J21DW014)

大连工业大学学报

OA北大核心CSTPCD

1674-1404

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