分析测试学报2013，Vol.32Issue(6)：772-775,4.DOI:10.3969/j.issn.1004-4957.2013.06.022
IRMOF-3配位共价修饰化合物的固态发光性质研究
Postsynthetic Covalent Modification of IRMOF-3 and Its Luminescence Properties
摘要
Abstract
An isoreticular metal-organic framework (IRMOF-3) was modified with salicylaldehyde (sal) by postsynthetic modification(PSM) method.The compound was metallated with M (acac)n (M =Mg,Zn,Pr,Ni) and the characteristics of the complex of IRMOF-3-Msal were investigated by solid-state fluorescence spectroscopy.The emission peaks of IRMOF-3-Znsal exhibited the maximum blue shifted behavior and stronger relative fluorescence intensity.The further research indicated the fluorescence variations of IRMOF-3-sal metallated with M (NO3) n were better than that with M (acac) n.关键词
IRMOF-3/金属有机框架化合物/后合成修饰/固态荧光Key words
IRMOF-3 / metal-organic frameworks / post-synthetic modification / solid-fluorescence分类
化学化工引用本文复制引用
汪淑华,李鹏飞,王正仁,张宁..IRMOF-3配位共价修饰化合物的固态发光性质研究[J].分析测试学报,2013,32(6):772-775,4.基金项目
国家自然科学基金项目(21261017) （21261017）
江西省自然科学基金项目(20122BAB213003) （20122BAB213003）
