化工学报2013，Vol.64Issue(4)：1312-1317,6.DOI:10.3969/j.issn.0438-1157.2013.04.027
乙烯淤浆聚合动态分子量分布模拟计算
Dynamic simulation of molecular weight distribution of ethylene slurry polymerization
摘要
Abstract
Based on the dynamic model of ethylene slurry polymerization, a decoupling method was proposed for rigorous model calculation of molecular weight distribution (MWD). The MWD model in large scale differential-algebraic equations (DAEs) was decoupled to a moment model in small scale DAEs and chain length based MWD in large scale ordinary differential equations (ODEs). The variable decoupling method was further proposed to solve the large scale ODEs through numerical computation. Comparison of the MWD curves with Flory distribution calculation was also presented and discussed.关键词
乙烯淤浆聚合/动态模拟/分子量分布Key words
ethylene slurry polymerization/ dynamic model/ molecular weight distribution分类
化学化工引用本文复制引用
奂金龙,占志良,陈曦,邵之江,姚臻,顾雪萍,冯连芳..乙烯淤浆聚合动态分子量分布模拟计算[J].化工学报,2013,64(4):1312-1317,6.基金项目
国家重点基础研究发展计划项目(2012CB720503) （2012CB720503）
国家自然科学基金项目(61074148) （61074148）
中央高校基本科研业务费专项资金. （）
