林产化学与工业2013，Vol.33Issue(3)：100-104,5.DOI:10.3969/j.issn.0253-2417.2013.03.019
固体酸Amberlyst 15催化合成丙烯酸异冰片酯
Synthesis of Isobornyl Acrylate in the Presence of Amberlyst 15
摘要
Abstract
Functional monomer-isobornyl acrylate was prepared from camphene and acrylic acid using cation exchange resin-Amberlyst 15 as catalyst.Effects of material ratio of camphene to acrylic acid,content of catalyst,types and content of inhibitors,the temperature,and the reaction time on reaction were investigated.Experimental results showed that the optimum conditions were material ratio of acrylic acid to camphene 1.3∶ 1,content of catalyst 12 ％,content of phenothiazine 0.03 ％,and the reaction temperature 60 ℃.The yield of isobornyl acrylate was 83.3 ％,and the selectivity was 94.6 ％ under the above conditions.The structure of isobornyl acrylate was characterized by FT-IR and GC-MS.关键词
丙烯酸异冰片酯/莰烯/酯化/阳离子树脂Key words
isobornyl acrylate/ camphene/ esterification/ cation exchange resin分类
化学化工引用本文复制引用
徐晓维,徐徐,王石发,花宇..固体酸Amberlyst 15催化合成丙烯酸异冰片酯[J].林产化学与工业,2013,33(3):100-104,5.基金项目
国家林业局林业公益性项目(201104015) （201104015）
国家自然科学基金项目(30972316) （30972316）
江苏省生物质能源与材料重点实验室开放基金项目(JSBEM201204) （JSBEM201204）
