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添加剂在加氢精制催化剂中作用的研究进展

张韶平 殷长龙 赵蕾艳 王晓 柳云骐 刘晨光

石油化工2013,Vol.42Issue(2):236-242,7.
石油化工2013,Vol.42Issue(2):236-242,7.

添加剂在加氢精制催化剂中作用的研究进展

Progresses in Research of Additives for Hydrorefining Catalysts

张韶平 1殷长龙 1赵蕾艳 1王晓 2柳云骐 1刘晨光1

作者信息

  • 1. 中国石油大学(华东)重质油国家重点实验室CNPC催化重点实验室,山东青岛266580
  • 2. 中国石油抚顺石化分公司,辽宁抚顺113000
  • 折叠

摘要

Abstract

Secondary additives(such as fluorine,boron and phosphorus) and complexing agents (such as citric acid,nitrilotriacetic acid and ethylenediamine tetraacetic acid) are main additives for hydrorefining catalysts.The effects of the two kinds of additives on the hydrorefining catalysts were introduced,and the way of the additives introduction,the effects and the action mechanism were discussed.The main roles of the additives could be concluded as follows:weakening the interaction between metals and supports,promoting the dispersion of metals on the surface of supports,improving the structure of the active phases of the catalysts and strengthening the acidity of the catalysts.However,it was still controversial how the additives enhanced catalyst acidity and affected the metal dispersion.

关键词

加氢精制催化剂/添加剂/第二助剂/络合剂

Key words

hydrorefining catalysts/ additives/ secondary additive/ complexing agent

分类

能源科技

引用本文复制引用

张韶平,殷长龙,赵蕾艳,王晓,柳云骐,刘晨光..添加剂在加氢精制催化剂中作用的研究进展[J].石油化工,2013,42(2):236-242,7.

基金项目

国家重点基础研究发展计划项目(2010CB226905) (2010CB226905)

中央高校基本科研业务费专项资金资助. ()

石油化工

OA北大核心CSCDCSTPCD

1000-8144

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