石油化工高等学校学报2013，Vol.26Issue(3)：9-12,4.DOI:10.3969/j.issn.1006-396X.2013.03.003
不同催化剂对渣油加氢反应产物分布的影响
Influence of Catalysts on Product Distribution of Residue Hydrotreating
摘要
Abstract
The influence of different catalysts on product distribution of residue hydrotreating in an autoclave with Tahe atmospheric residue (THAR) and Saudi Arabia light crude oil vacuum residue (ALVR) was studied.The results show that the catalyst activity and selectivity can be evaluated by the cracking conversion for unit coking (x1/xcoke) or the ratio of the cracking conversion to the unit condensation (x1/x2).It is consistent to the traditional understanding of residue hydrotreating.The catalysts influenced product distribution by providing active hydrogen atom to inhibit cracking of macromolecular radicals.There is different performance to inhibit coke formation in residue hydrotreating for different catalysts.The inhibition condensation sequence of catalysts is B＞C＞A and the maximum difference of the ratio of the cracking conversion to the unit condensation can reach 4.3.The influence of catalysts on residue hydrotreating was not only related to content and species of active metals,but also to the atomic ratio of hydrogenating component and surface structure of catalyst.关键词
渣油加氢/催化剂/产物分布/生焦Key words
Residue hydrotreating/ Catalyst/ Product distribution/ Coking分类
能源科技引用本文复制引用
孙昱东,谷志杰,杨朝合..不同催化剂对渣油加氢反应产物分布的影响[J].石油化工高等学校学报,2013,26(3):9-12,4.基金项目
中央高校基本科研业务费专项基金项目(11CX05008A) （11CX05008A）
中国石油科技创新基金项目(2011D-5006-0405) （2011D-5006-0405）
中石油重大科技专项(10-01A-05-01-04). （10-01A-05-01-04）
