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有机小分子/膨胀石墨复合相变材料的制备及性能

费鹏飞 西鹏 程博闻

天津工业大学学报2013,Vol.32Issue(3):14-18,5.
天津工业大学学报2013,Vol.32Issue(3):14-18,5.

有机小分子/膨胀石墨复合相变材料的制备及性能

Fabrication and characterization of small organic molecules/expansion graphite composite phase change materials

费鹏飞 1西鹏 1程博闻2

作者信息

  • 1. 天津工业大学材料科学与工程学院,天津300387
  • 2. 中国科学院化学研究所高分子物理与化学国家重点实验室,北京100080
  • 折叠

摘要

Abstract

The phase change materials of small organic molecules as functional materials are loaded to vermicular slit porous expansion graphite carrier through the vacuum-load method,and the composite phase change materials with good phase change performance and stable mechanical properties are prepared.Wide-angle X-ray diffraction (XRD) measurements,differential scanning calorimeter (DSC),field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM) were employed respectively to investigate their structure,thermal properties and load effect.The results show that with the help of the nanoscale slit confinement effect of the expanded graphite as well as heterogeneous nucleation of composite phase change materials after loaded process in expanded graphite,small organic molecule phase change units keep the structural stability,and lattice structure become more regular and the crystallinity increased obviously.The whole of the composite phase change materials show excellent phase transformation function.The supercooling phenomenon of phase change process is also significantly improved.

关键词

相变材料/膨胀石墨/过冷度

Key words

composite phase change materials/ expansion graphite/ supercooling degree

分类

通用工业技术

引用本文复制引用

费鹏飞,西鹏,程博闻..有机小分子/膨胀石墨复合相变材料的制备及性能[J].天津工业大学学报,2013,32(3):14-18,5.

基金项目

国家自然科学基金资助项目(51203112) (51203112)

中国纺织工业协会资助项目(2009076) (2009076)

天津工业大学学报

OA北大核心CSTPCD

1671-024X

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