陕西科技大学学报(自然科学版)2013,Vol.31Issue(4):24-28,37,6.
立方体形Ag3PO4可见光光催化剂的制备及其性能研究
Synthesis and characterization of cubic Ag3PO4 visible light photocatalyst
摘要
Abstract
Cubic silver orthophosphate photocatalyst with good activity was successfully fabricated through a simple silver-ammine assisted method by using AgNO3,Na2HPO4 and NH3 · H2O.X-ray powder diffraction,scanning electron microscopy,Fourier transform infrared spectrometer and UV-vis diffuse reflectance spectrometer were employed to investigate the phase structure,micro morphology and absorbance of Ag3PO4 powders.The photocatalytic activity of Ag3PO4 photocatalyst was tested by the photocatalytic degradation of Rhodamine B aqueous solution under the simulated sunlight irradiation.The results reveal that the asprepared cubic Ag3PO4 crystals are bounded entirely by six of [100] facets and exhibit much better photocatalytic activity than spheres.This is due to the higher absorption efficiency of the visible light photons,effectively separation of electrons and holes and catalytically activesites on their surfaces of cubic silver orthophosphate photocatalyst which is dominated by the highly active [100] facets.关键词
磷酸银/可见光光催化剂/罗丹明B/光催化Key words
Ag3PO4/ visible photocatalyst/ RhB/ photocatalysis分类
化学引用本文复制引用
李军奇,郭占云,王德方,王玉..立方体形Ag3PO4可见光光催化剂的制备及其性能研究[J].陕西科技大学学报(自然科学版),2013,31(4):24-28,37,6.基金项目
国家自然科学基金项目(51203136) (51203136)
陕西科技大学学术骨干培育计划项目(XSGP201202) (XSGP201202)
陕西科技大学自然科学基金项目(ZX11-14) (ZX11-14)