印染助剂2013，Vol.30Issue(6)：6-8,3.
有机硅双子表面活性剂的合成研究
Study on synthesis of organic silicon gemini surfactant
摘要
Abstract
Polyether modified organic silicon gemini surfactant was synthesized from 3-(2-aminoethyl)-aminopropyl methyl dimethoxy silane (D602),hexamethyldisiloxane (MM),ethylene glycol diglycidyl ether and acetic anhydride through three steps.The influences of reactant molar ratio (oxethyl aminoethyl-aminopropyl siloxane and acetic anhydride),reaction temperature and reaction time on the reaction yields were investigated.The optimized synthesis conditions of polyether modified organic silicon gemini surfactant were confirmed through the single factor experiment:the molar ratio of oxethyl aminoethyl-aminopropyl siloxane and acetic anhydride was 1:4,isopropanol as solvent,reacted at 60 ℃ for 2 h,and the synthesis conditions of product were mild,easy to control.The product structure was confirmed by 1H-NMR.关键词
有机硅双子表面活性剂/合成/表征Key words
organic silicon gemini surfactant/ synthesis/ characterization分类
化学化工引用本文复制引用
邢凤兰,李兴涛,冯俊,王丽艳,徐群..有机硅双子表面活性剂的合成研究[J].印染助剂,2013,30(6):6-8,3.基金项目
黑龙江省教育厅2011年度科研项目(12511589) （12511589）
2010年度科研项目(11551531) （11551531）
