应用化学2013，Vol.30Issue(7)：834-839,6.DOI:10.3724/SP.J.1095.2013.20336
孔雀石绿分子印迹聚合物的制备及其吸附
Preparation and Adsorption of Molecularly Imprinting Polymer for Malachite Green
摘要
Abstract
A molecularly imprinted polymer (MIP) of malachite green (MG) was prepared through bulk polymerization.Polymerization conditions,such as the kinds and the dosages of functional monomers,the dosages of cross linker,the concentrations of the template,as well as the polymerization time,were optimized.Static equilibrium binding method was employed to investigate the absorption ability of polymers to MG.The result showed that when using MAA as monomer and the molar ratio of MG,MAA,EGDMA was 1∶4∶20,the largest amount of absorption was achieved and the imprinting factor(α =QMIP/QNIP) could be as large as 3.6,indicating that the MIP prepared in this work had the excellent ability of recognition and enrichment for MG.关键词
孔雀石绿/分子印迹聚合物/本体聚合法/吸附性能Key words
Malachite green/ molecularly imprinted polymer/bulk polymerization/ absorption分类
化学化工引用本文复制引用
吴泉书,黄志勇,林郑忠..孔雀石绿分子印迹聚合物的制备及其吸附[J].应用化学,2013,30(7):834-839,6.基金项目
国家自然科学基金资助项目(40771185) （40771185）
福建省基金资助项目(2012J01046) （2012J01046）
福建省科技重点项目(2012Y0052) （2012Y0052）
集美大学创新团队基金资助项目(2010A007) （2010A007）
集美大学优秀青年骨干教师基金资助项目(2009C004) （2009C004）
教育部留学回国人员科研启动基金资助项目 （）
