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NaA分子筛膜渗透蒸发制备高纯糠醛

周志辉 丁武龙 王涛 刘小青 刘恒浪 王金渠

石油化工2013,Vol.42Issue(3):292-297,6.
石油化工2013,Vol.42Issue(3):292-297,6.

NaA分子筛膜渗透蒸发制备高纯糠醛

Preparation of High-Pure Furfural Through Pervaporation on NaA Zeolite Membranes

周志辉 1丁武龙 1王涛 1刘小青 1刘恒浪 1王金渠2

作者信息

  • 1. 武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室,湖北武汉430081
  • 2. 大连理工大学精细化工国家重点实验室,辽宁大连116024
  • 折叠

摘要

Abstract

Continuous and compact NaA zeolite membranes were synthesized by a hot dip-coating seeding method and applied to the preparation of high pure furfural by dehydration.The effects of feeding flowrate,feedstock temperature and furfural content in the feedstock on the dehydration of furfural were investigated.The results indicated that under the conditions of feedstock temperature 80 ℃,pressure of the penetrating side less than 100 Pa,feeding flowrate 196 mL/min and furfural content in the feedstock 93.7%(w),the separation factor of the NaA membranes could reach 34 110.Under the conditions of feedstock temperature 90 ℃ and separation factor 12 000,the flux could reach 1.79 kg/(m2 · h).The furfural content in the products was 99.5%(w) and the average penetration flux on the membranes was 0.60 kg/(m2 · h) when the furfural content in the feedstock was 89.6%(w) and after continuous pervaporation was carried out for 96 h.

关键词

NaA分子筛膜/渗透蒸发/糠醛脱水

Key words

NaA zeolite membrane/ pervaporation/ furfural dehydration

分类

化学化工

引用本文复制引用

周志辉,丁武龙,王涛,刘小青,刘恒浪,王金渠..NaA分子筛膜渗透蒸发制备高纯糠醛[J].石油化工,2013,42(3):292-297,6.

基金项目

武汉市科技局重大项目(200861113462). (200861113462)

石油化工

OA北大核心CSCDCSTPCD

1000-8144

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