石油化工2013，Vol.42Issue(4)：411-414,4.
渣油加氢脱残炭催化剂的失活研究
Deactivation of Catalyst for Removing Residue Carbon in Hydrotreating Residual Oil
崔瑞利 1赵愉生 1于双林 1任春晓 1张志国 1范建光1
作者信息
- 1. 中国石油石油化工研究院,北京100195
- 折叠
摘要
Abstract
The deactivation of the catalyst for removing residual carbon in hydrotreating residue oil was studied by means of BET,ICP,elementary analysis,Raman spectrometry and TEM.It was shown that the coke forming on the spent catalyst was as much as 24.57％(w),and the coke distribution along the radial of the catalyst pellets was V-shape,which led to the pore diameters deceasing and the diffusion resistance increasing.It was found that the MoS2 phases were longer and the number of its piles was more after running.It was suggested that the resistance to coke formation and the stability of MoS2 phase at high temperature should be enhanced to improve the stability of the catalyst.During running,temperature runaway and hot spot should also be avoided.关键词
渣油/加氢/脱残炭/积碳/催化剂失活Key words
residual oil/ hydrotreating/ removing residue carbon/ coke deposition/ deactivation of catalyst分类
化学化工引用本文复制引用
崔瑞利,赵愉生,于双林,任春晓,张志国,范建光..渣油加氢脱残炭催化剂的失活研究[J].石油化工,2013,42(4):411-414,4.
