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BCE催化剂制备高密度聚乙烯管材料

孙怡菁 周俊领 郭子芳 马东

石油化工2013,Vol.42Issue(5):547-550,4.
石油化工2013,Vol.42Issue(5):547-550,4.

BCE催化剂制备高密度聚乙烯管材料

Application of BCE Catalyst in Preparation of High Density Polyethylene Pipe Resins

孙怡菁 1周俊领 1郭子芳 1马东1

作者信息

  • 1. 中国石化北京化工研究院,北京 100013
  • 折叠

摘要

Abstract

The compositions,particle size distributions and copolymerization performances of BCE catalyst and a commercial catalyst(Cat A),and the fines content in the polymers prepared with the two catalysts were investigated by means of spectrophotometry,titration,particle size distribution meter and 13C NMR.The results show that BCE catalyst has the features of less fines content,narrower particle size distribution and better copolymerization performance,and the polymer prepared with BCE contains less fines.As for the preparation of HDPE pipe resin with BCE catalyst,the solid content in the mother liquid is averagely reduced by 11%(w) compared to Cat A catalyst.The PE pipe resin prepared with BCE catalyst possesses slow crack growth resistance,which can meet the national standard,and good hydrostatic pressure resistance.

关键词

BCE催化剂/聚乙烯/淤浆聚合/管材料

Key words

BCE catalyst/ polyethylene/ slurry polymerization/ pipe resin

分类

化学化工

引用本文复制引用

孙怡菁,周俊领,郭子芳,马东..BCE催化剂制备高密度聚乙烯管材料[J].石油化工,2013,42(5):547-550,4.

石油化工

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