石油化工2013，Vol.42Issue(5)：568-576,9.
脂肪族聚碳酸酯的研究进展
Progresses in Research of Aliphatic Polycarbonates
摘要
Abstract
The catalysts for the synthesis of aliphatic polycarbonates(APCs) were summarized according to three reaction systems,namely the copolymerization of carbon dioxide with epoxides,the ring-opening polymerization of cyclic carbonates and the two-step polycondensation of dialkyl carbonates and aliphatic diols.Particularly,the new research achievements for the catalysts and the mechanism of the reactions were introduced.The relationship between the structures and the performances of APCs,such as biodegradability and thermal decomposition,were discussed.The applications of APCs in medical materials,ceramics,rubber industry and so on were introduced.The synthesis of APCs by different methods were analyzed briefly.The development trend of APCs in future was forecasted.关键词
脂肪族聚碳酸酯/催化剂/环状碳酸酯/脂肪族二元醇/碳酸二甲酯/碳酸二苯酯/二氧化碳Key words
aliphatic polycarbonates/ catalyst/ cyclic carbonate/ aliphatic diols/ dimethyl carbonate/ diphenyl carbonate/ carbon dioxide分类
化学化工引用本文复制引用
刘峰,翟刚,李建国,刘绍英,杨先贵,王公应..脂肪族聚碳酸酯的研究进展[J].石油化工,2013,42(5):568-576,9.基金项目
"十二五"国家科技支撑计划项目(2013BAC11B05). （2013BAC11B05）
