石油化工2013，Vol.42Issue(6)：589-596,8.
后过渡金属催化烯烃聚合稳定性的改进
Progress in Thermostability of Late Transition Metal Catalysts for Olefin Polymerization
廖恒 1伍青1
作者信息
- 1. 中山大学化学与化学T程学院高分子研究所,广东广州510275
- 折叠
摘要
Abstract
The characteristics of late transition metal catalysts relative to early transition metal catalysts in the catalytic polymerization of olefins are simply described.Late transition metal catalysts with several types of ligands are introduced and the factors affecting the catalyst thermostability are summarized by comparing the relative molecular mass of the obtained polymers,the catalytic activity for olefin polymerization and the sustainable time of the activity.In general,the proper adjustment of the steric hindrance and electronic effect of the ligands toward the metal centers and a rational design of ligand structure can effectively improve the thermostability of the late transition metal catalysts.关键词
后过渡金属催化剂/烯烃聚合/乙烯聚合/热稳定性Key words
late transition metal catalysts/ olefin polymerization/ ethylene polymerization/thermostability分类
化学化工引用本文复制引用
廖恒,伍青..后过渡金属催化烯烃聚合稳定性的改进[J].石油化工,2013,42(6):589-596,8.
