石油化工2013，Vol.42Issue(6)：651-655,5.
具有表面活性的两亲性聚合物SL-1的合成及其乳化性能
Synthesis and Emulsion Properties of an Amphiphilic Copolymer SL-1 with Surface Activity
许星光 1欧阳坚 1朱卓岩 1王凤 1王源源1
作者信息
- 1. 中国石油勘探开发研究院油田化学研究所,北京100083
- 折叠
摘要
Abstract
With potassium persulfate/sodium bisulfite as a redox initiator system,an amphiphilic copolymer SL-1 with surface activity was synthesized from acrylamide and surface active monomer (YS) with pendant groups including sulfonic group,ester group and long-chain alkyl group,etc.by free radical solution copolymerization,and was characterized by means of FTIR.The influence of polymer concentration on the interfacial tension between SL-1 and Daqing crude oil was investigated.The results show that the interfacial tension decreases to minimum of 7.84 mN/m with increasing the polymer concentration.Factors affecting the stability of the emulsion formed by Daqing crude oil and SL-1 solution were studied.The results show that the emulsion with 1 500 mg/L SL-1 solution,which contains 2.0％ (x) YS,has good stability when it is applied in the oil reservoir with temperature of lower than 80 ℃ and salinity of about 5 000-25 000 mg/L.关键词
表面活性/两亲性聚合物/自由基共聚/乳化性能Key words
surface activity/ amphiphilic copolymer/ free radical polymerization/ emulsion property分类
化学化工引用本文复制引用
许星光,欧阳坚,朱卓岩,王凤,王源源..具有表面活性的两亲性聚合物SL-1的合成及其乳化性能[J].石油化工,2013,42(6):651-655,5.
