石油化工2013,Vol.42Issue(6):676-680,5.
β-环糊精交联聚合物对铜、铅和锌的吸附性能
Adsorptivity of Acrylamide/β-Cyclodextrin Acylated/Allyl-Biphenyl Ether Crosslinked Copolymer for Cu2+, Pb2+ and Zn2+
摘要
Abstract
β-cyclodextrin crosslinked copolymer AM/β-CD-AA/ABE was synthesized by crosslinking β-cyclodextrin acylated(β-CD-AA) with allyl-biphenyl-ether(ABE):acrylamide(AM) and N,N-methylene double propionamide,and characterized by means of FTIR and TG.The effects of the initial mass concentrations of metal ions(Cu2+,Pb2+ and Zn2+),ion solutionpH and temperature on the adsorptivity of the copolymer were investigated.The results show that the adsorption capacities of AM/β-CD-AA/ABE copolymer for Cu2+,Pb2+ and Zn2+ in solutions are different,among which the static adsorption capacity for Zn2+ is the maximum,50.1 mg/g under the conditions of 35 ℃,initial mass concentration of Zn2+ 200 mg/L and pH 3-4.The adsorption equilibriums of Cu2+,Pb2+ and Zn2+ on the copolymer accord with Freundlich adsorption isotherm.关键词
丙烯酸β-环糊精酯聚合物/微波/重金属/吸附能力Key words
acrylic acid-β-cyclodextrin ester copolymer/ microwave/ heavy metals/ adsorption capacity分类
化学化工引用本文复制引用
赵梦奇,买地尼亚提·巴斯提,司马义·努尔拉..β-环糊精交联聚合物对铜、铅和锌的吸附性能[J].石油化工,2013,42(6):676-680,5.基金项目
新疆维吾尔族自治区自然科学基金项目(200821123) (200821123)
国家自然科学基金项目(21063013,21064009). (21063013,21064009)