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β-环糊精交联聚合物对铜、铅和锌的吸附性能

赵梦奇 买地尼亚提·巴斯提 司马义·努尔拉

石油化工2013,Vol.42Issue(6):676-680,5.
石油化工2013,Vol.42Issue(6):676-680,5.

β-环糊精交联聚合物对铜、铅和锌的吸附性能

Adsorptivity of Acrylamide/β-Cyclodextrin Acylated/Allyl-Biphenyl Ether Crosslinked Copolymer for Cu2+, Pb2+ and Zn2+

赵梦奇 1买地尼亚提·巴斯提 2司马义·努尔拉1

作者信息

  • 1. 新疆大学化学化工学院,新疆乌鲁木齐830046
  • 2. 新疆农业大学化工学院,新疆乌鲁木齐830052
  • 折叠

摘要

Abstract

β-cyclodextrin crosslinked copolymer AM/β-CD-AA/ABE was synthesized by crosslinking β-cyclodextrin acylated(β-CD-AA) with allyl-biphenyl-ether(ABE):acrylamide(AM) and N,N-methylene double propionamide,and characterized by means of FTIR and TG.The effects of the initial mass concentrations of metal ions(Cu2+,Pb2+ and Zn2+),ion solutionpH and temperature on the adsorptivity of the copolymer were investigated.The results show that the adsorption capacities of AM/β-CD-AA/ABE copolymer for Cu2+,Pb2+ and Zn2+ in solutions are different,among which the static adsorption capacity for Zn2+ is the maximum,50.1 mg/g under the conditions of 35 ℃,initial mass concentration of Zn2+ 200 mg/L and pH 3-4.The adsorption equilibriums of Cu2+,Pb2+ and Zn2+ on the copolymer accord with Freundlich adsorption isotherm.

关键词

丙烯酸β-环糊精酯聚合物/微波/重金属/吸附能力

Key words

acrylic acid-β-cyclodextrin ester copolymer/ microwave/ heavy metals/ adsorption capacity

分类

化学化工

引用本文复制引用

赵梦奇,买地尼亚提·巴斯提,司马义·努尔拉..β-环糊精交联聚合物对铜、铅和锌的吸附性能[J].石油化工,2013,42(6):676-680,5.

基金项目

新疆维吾尔族自治区自然科学基金项目(200821123) (200821123)

国家自然科学基金项目(21063013,21064009). (21063013,21064009)

石油化工

OA北大核心CSCDCSTPCD

1000-8144

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