辽宁石油化工大学学报2013，Vol.33Issue(1)：25-29,5.DOI:10.3696/j.issn.1672-6952.2013.01.008
金属有机骨架化合物Co1Cu2(BHTC)2的合成及生长机理探索
Preparation and Growth Mechanism of Metal Organic Frameworks Co1Cu2(BHTC)2
李永超 1刘宗琦 2辛春玲 1田晓光 1侯俊琦 1田世超 1卞婉莹 1连丕勇1
作者信息
- 1. 辽宁石油化工大学石油化工学院,辽宁抚顺113001
- 2. 中国石油辽阳石化分公司,辽宁辽阳111003
- 折叠
摘要
Abstract
Metal organic frameworks Co1Cu2 (BHTC)2 was prepared from bipheny1-3,4,5-tricarboxylate as organic ligand with hydrothermal method,and then characterized by XRD,SEM,TEM,TGA and FT-IR technology.The effect of temperature and crystallization time on the crystal growth and the growth mechanism of Co1Cu2 (BHTC)2 was studied by SEM method.This work provides a new way of the crystal growth of nanoporous material.The results indicate that the crystal morphology changes markedly with the increase of crystallized time.The small hexagonal secondary building units (SBUs) were assembled by sharing the same prism of the tiny crystals,and then aggregated into a bulk hexagonal plate-like crystal.关键词
金属有机骨架化合物/水热合成法/晶体/生长机理Key words
Metal organic frameworks/ Hydrothermal method/ Crystal/ Growth mechanism.分类
能源科技引用本文复制引用
李永超,刘宗琦,辛春玲,田晓光,侯俊琦,田世超,卞婉莹,连丕勇..金属有机骨架化合物Co1Cu2(BHTC)2的合成及生长机理探索[J].辽宁石油化工大学学报,2013,33(1):25-29,5.
