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导电聚苯胺/镀镍碳纳米管复合材料的制备与研究

何征 齐暑华 邱华 秦云川

航空材料学报2013,Vol.33Issue(4):53-57,5.
航空材料学报2013,Vol.33Issue(4):53-57,5.DOI:10.3969/j.issn.1005-5053.2013.4.010

导电聚苯胺/镀镍碳纳米管复合材料的制备与研究

Preparation and Properties of Polyaniline/Ni-Coated Carbon Nanotubes Composites

何征 1齐暑华 1邱华 1秦云川1

作者信息

  • 1. 西北工业大学理学院应用化学系,西安710129
  • 折叠

摘要

Abstract

By using electroless plating,metal nickel (Ni) was coated on the surface of carbon nanotubes (CNTs) and the composites Ni/CNTs were prepared.Then conductive polyaniline (PANI) was synthesized by in situ polymerization using ammonium persulfate as the oxidant.After that,the composites PANI/Ni/CNTs were prepared through the solution blending method.The morphologies and performance of the composites were characterized by transmission electron microscope (TEM),energy dispersive spectroscopy (EDS),fourier transmission infrared (FT-IR),UV-Visible Spectrophotometer (UV-Vis),X-ray diffraction analysis (XRD) and two probe method.Results show that the lengths of Ni/CNTs are hundreds of nanometer to tens of microns,and the thickness of the coating is about 20-30 nm.With Ni/CNTs contents increasing,the conductivities of the composites PANI/Ni/CNTs also increase.The percolation threshold value of it is about 3.5%.

关键词

聚苯胺/碳纳米管/化学镀镍/电性能

Key words

polyaniline/ carbon nanotubes/ electroless nickel plating/ electrical property

分类

航空航天

引用本文复制引用

何征,齐暑华,邱华,秦云川..导电聚苯胺/镀镍碳纳米管复合材料的制备与研究[J].航空材料学报,2013,33(4):53-57,5.

基金项目

西北工业大学基础研究基金(JC20110230) (JC20110230)

航空材料学报

OA北大核心CSCDCSTPCD

1005-5053

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