华中师范大学学报（自然科学版）2013，Vol.47Issue(3)：357-360,4.
H6P2W9Mo9O62·24H2O催化清洁氧化环己酮合成己二酸
Clear oxidation of cyclohexanone to adipic acid catalyzed by H6P2W9Mo9O62·24H2O
摘要
Abstract
Tungstomolybdophosphate acid with Dawson structure was prepared by hydrothermal synthesis and characted by means of FT-IR,TG-DTA.The synthesis of adipic acid with cyclohexanone and 30 percent hydrogen peroxide was carried out as a probe reaction to study the catalytic activity.The main effects of the reaction were optimized with orthogonal experiments,the mechanism was proposed.The results showed that under the optimal condition,i.e.the mole ratio of C6H10O ∶ H2O2 ∶ H2C2O4 ∶H6P2W9Mo9O62 · 24H2O=100 ∶ 400 ∶ 1.00 ∶ 0.15,the reaction temperature was 100℃,irradiation time 5 h,the isolated yield of adipic acid could reach 71.6％ and its purity was 99.7％.The filtration containing the catalyst could be concentrated by the rotary evaporation and be reused five times by easily separation of the product after reaction,the isolated yield of adipic acid was still above 50.3 ％.关键词
H6P2W9Mo9O62·24H2O/Dawson结构/催化氧化/己二酸/环己酮Key words
H6P2W9Mo9O62 · 24H2O / Dawson structure/ hydrothermal synthesis / adipic acid/ cyclohexanone分类
化学化工引用本文复制引用
徐常龙,严平,曹小华,谢宝华,杨丹..H6P2W9Mo9O62·24H2O催化清洁氧化环己酮合成己二酸[J].华中师范大学学报（自然科学版）,2013,47(3):357-360,4.基金项目
国家自然科学基金项目(21161009) （21161009）
江西省自然科学基金项目(20132BAB203004) （20132BAB203004）
江西省教育厅科技资助项目(GJJ10626,GJJ11613). （GJJ10626,GJJ11613）
