玻璃钢/复合材料Issue(4)：12-15,4.
微波法合成新型双酚A二苯醚型双马来酰亚胺研究
SYNTHESIS OF 4,4-DIPHENYL BISPHENOL A ETHER BISMALEIMIDE UNDER MICROWAVE IRRADIATION
摘要
Abstract
Using maleic anhydride and 2,2'-bis [4-(4-aminophenox) phenyl] propane as raw materials,a no-vel bismalemide monomer,2,2'-bis [4-(4-maleimidophenox) phenyl] propane (BPA-BMI) was synthesized undermicrowave irradiation.The structure of compound was confirmed by FT-IR spectra,1H-NMR and MS.On the basisof orthogonal design,the optimal preparation conditions for BPA-BMI under microwave irradiation was as follows:themola ratio of maleic anhydride to BAPP was 2.3:1,catalyst amount was 10％ (wt％),microwave power was 450Wand radiation time was 30min.The highest yield of product was 67.26％.Compared with tradition preparation ofBMI,the method of microwave irradiation is convenient,quick and less pollution.关键词
微波辐射/2,2′-双[4-(马来酰亚胺基苯氧基)苯基]丙烷/正交试验Key words
microwave irradiation / 2,2'-bis [4-(4-maleimidophenox) phenyl] propane / orthogonal design分类
通用工业技术引用本文复制引用
李鹏,张衍,刘育建,方俊..微波法合成新型双酚A二苯醚型双马来酰亚胺研究[J].玻璃钢/复合材料,2013,(4):12-15,4.基金项目
上海市重点学科资助(B502) （B502）
