色谱2013，Vol.31Issue(7)：674-678,5.DOI:10.3724/SP.J.1123.2013.05001
常见食品中邻苯二甲酸酯类增塑剂含量及食品包装材料中邻苯二甲酸酯类增塑剂迁移量的测定
Determination of phthalate plasticizers in daily foods and their migration from food packages
摘要
Abstract
A total of 16 phthalates in food samples (beverage,milk and wine) were analyzed by gas chromatography-mass spectrometry (GC-MS) combined with the sample preparation of liquid-liquid extraction and dispersive solid-phase extraction (dSPE).The limits of detection (LODs,S/N =3) for the 16 phthalates were fairly good,ranging from 0.005 to 0.025 mg/L.The relative standard deviations (RSDs) of the peak areas were less than 2％,showing good repeatability.In addition,the recoveries of phthalates in various matrices were generally ranging from 60％ to 1 10％.In conclusion,the developed method can help the trace analysis of phthalates in beverage,wine and milk.In order to strictly investigate the migration of phthalates from the daily food packages like plastic wraps and storage bags,iso-octane was used as the simulant of fatty foods.The migration determined using the above optimized method showing the significant migration existing in plastic wraps and some unqualified products in current market is not meeting the national regulations about the migration limits of phthalates.关键词
气相色谱-质谱联用/基质分散固相萃取/邻苯二甲酸酯/增塑剂/食品/包装材料Key words
gas chromatography-mass spectrometry/dispersive solid-phase extraction/phthalates/plasticizers/foods/food packages分类
化学化工引用本文复制引用
杨悠悠,谢云峰,田菲菲,杨永坛..常见食品中邻苯二甲酸酯类增塑剂含量及食品包装材料中邻苯二甲酸酯类增塑剂迁移量的测定[J].色谱,2013,31(7):674-678,5.基金项目
中粮集团公司资助项目(2012-C3-F001). （2012-C3-F001）
