高压物理学报2013，Vol.27Issue(2)：253-260,8.
室温离子液体[Emim][PF6]和[Bmim][PF6]压致相变的拉曼散射研究
Pressure-Induced Phase Transition of [Emim][PF6] and [Bmim] [PF6] Studied by Raman Scattering
摘要
Abstract
In-situ pressure-induced phase transition of ionic liquids [Emim] [PF6] and [Bmim] [PF6] have been studied under high pressure and room temperature by usingRaman spectroscopy and highpressure diamond anvil cell (DAC) apparatus.With the increase of pressure,[Emim][PF6] experiences the solid-solid phase transition at about 0.86 GPa,and [Bmim][PF6] experiences the liquid-solid phase transition at about 0.62 GPa and the solid-solid phase transition at about 1.45 GPa.Furthermore,the decrease of pressure of [Bmim] [PF6] has also been discussed in details.Pressure-released Raman spectra shows that the phase transition of [Bmim][PF6] is reversible under pressure up to 2 GPa.关键词
室温离子液体/拉曼光谱/相变/高压Key words
room temperature ionic liquids/ Raman spectra/ phase transition/ high pressure分类
数理科学引用本文复制引用
朱祥,王永强,王征,程学瑞,袁朝圣,陈镇平,苏磊..室温离子液体[Emim][PF6]和[Bmim][PF6]压致相变的拉曼散射研究[J].高压物理学报,2013,27(2):253-260,8.基金项目
国家自然科学基金(21273206,51002144) （21273206,51002144）
河南省高等学校青年骨干教师资助计划(2010GGJS-110) （2010GGJS-110）
河南省教育厅自然科学基金(2009A140009) （2009A140009）
郑州轻工业学院博士科研基金 （）
