应用化学2013，Vol.30Issue(8)：867-871,5.DOI:10.3724/SP.J.1095.2013.20427
改进法合成1-苄基-3-烷基苯并三氮唑类离子液体及其表征
Improved Synthesis and Characterization of 1-Benzyl-3-alkylbenzotriazolium Ionic Liquids
摘要
Abstract
An improved procedure was developed for the synthesis of 1-benzyl-3-alkylbenzotriazolium ionic liquids from commercially available starting materials.The structures of target compounds were characterized by FT-IR,1H NMR and 13C NMR.The yield reaches 82.7％ ～86.1％ when the molar ratio of substituted alkyl benzotriazole to cuprous iodide and benzyl bromide is 10∶2.5∶ 11,and the reaction time is 5 ～ 6 h.Moreover,their solubility,the relationship between molecular structure and melting point of the ionic liquids were investigated.关键词
苯并三氮唑离子液体/催化/合成/表征Key words
benzotriazolium ionic liquids/ catalysis/ synthesis/ characterization分类
化学化工引用本文复制引用
宿连征,金诚,谷利军..改进法合成1-苄基-3-烷基苯并三氮唑类离子液体及其表征[J].应用化学,2013,30(8):867-871,5.基金项目
云南省教育厅科学研究基金项目(2010Y431) （2010Y431）
