电源技术2013，Vol.37Issue(8)：1314-1318,5.
碳源对核壳结构LiFePO4/C纳米复合正极材料性能影响
Effects of carbon resources on electrochemical performance of LiFePO4/C nanocomposites as cathode materials for lithium ion batteries
摘要
Abstract
Nano-sized LiFePO4/C with a core/shell structure was prepared by a two-step procedure,which involved the synthesis of FePO4/polyaniline (PANI) and subsequent thermal calcination in the presence of carbon sources.An initial coating of PANI on FePO4 could protect LiFePO4 nanopaticles from further growth,facilitating the fabrication of the nano-sized LiFePO4/C nanocomposites.Carbon sources,such as sucrose,polyethylene glycol or conductive carbon black,were found to have great effects on size,shape and electrochemical performance of LiFePO4/C nanocomposites.LiFePO4/C nanocomposites fabricated with sucrose as carbon source have relatively uniform sizes and higher contents of carbon,and exhibit the superior electrochemical performance.关键词
磷酸铁锂/聚苯胺/碳源/正极材料Key words
lithium iron phosphate/ polyaniline/ carbon resources/ cathode materials分类
信息技术与安全科学引用本文复制引用
张艳敏,蒋仲庆,蒋仲杰,房江华,郝晓刚..碳源对核壳结构LiFePO4/C纳米复合正极材料性能影响[J].电源技术,2013,37(8):1314-1318,5.基金项目
国家自然科学基金青年基金项目(11105078) （11105078）
宁波市自然科学基金(2011A610209) （2011A610209）
浙江省大学生新苗人才计划项目(2011R422007) （2011R422007）
宁波市科技创新团队(2011B82002) （2011B82002）
