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PEG用量对LiFePO4/C复合正极材料低温性能的影响

马金波 徐云龙 宋作玉

电源技术2013,Vol.37Issue(8):1329-1331,3.
电源技术2013,Vol.37Issue(8):1329-1331,3.

PEG用量对LiFePO4/C复合正极材料低温性能的影响

Effects of PEG dosage on low temperature performance of LiFePO4/C composite cathode material

马金波 1徐云龙 1宋作玉1

作者信息

  • 1. 华东理工大学材料科学与工程学院,超细材料制备与应用教育部重点实验室上海市先进聚合物材料重点实验室,上海200237
  • 折叠

摘要

Abstract

LiFePO4/C were prepared by liquid-phase method using polyethylene glycol (PEG) as carbon source and nano structure control agent,LiH2PO4 as lithium source and Fe (NO3)3·9 H2O as iron source.The charge/discharge test,EIS and scanning electron microscope (SEM) texts show that increasing the dosage of PEG can obtain the products with small particles,high lithium diffusion coefficient,and can improve its low temperature performance obviously.When n(PEG) ∶ n(LFP)=2.00 ∶ 1.00,the specific capacity of the battery can reach 111.7 mAh/g at -20 ℃ of 0.1 C rate,and the capacity fading radio is 1.8% after 20 cycles.

关键词

LiFePO4/聚乙二醇(PEG)/低温

Key words

LiFePO4/ polyethylene glycol (PEG)/ low temperature

分类

信息技术与安全科学

引用本文复制引用

马金波,徐云龙,宋作玉..PEG用量对LiFePO4/C复合正极材料低温性能的影响[J].电源技术,2013,37(8):1329-1331,3.

基金项目

上海市科学技术委员会"创新行动计划"(纳米专项0852nm02300) (纳米专项0852nm02300)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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