高等学校化学学报2013，Vol.34Issue(8)：1953-1958,6.DOI:10.7503/cjcu20121095
Al-LiBH4复合材料的制备与产氢性能
Preparation and Hydrogen Generation for Al-LiBH4 Composite Materials
摘要
Abstract
Al-LiBH4 composite materials were prepared by the mechanical ball milling.The results of the hydrogen-production curves and X-ray diffraction patterns show that when the reaction temperature is higher,the mutual promotion effect between aluminum and LiBH4 will be more intensed,and the generation of hydrogen will be more.The milled materials have good properties of hydrogen generation in water at room temperature,especially for the Al-25％ LiBH4(mass fraction of LiBH4 is 25％) material milled for 5 h with a ball/material ratio of 30 ∶ 1,which can produce 720 mL/g hydrogen.At 90 ℃,the Al-25 ％ LiBH4 material can produce 2026 mL/g hydrogen with the hydrogen yield of 95％ while the Al-30％ LiBH4 material can produce 2211mL/g hydrogen with the hydrogen yield of 96％.关键词
Al-LiBH4复合材料/微量热/制氢/机械球磨/X射线衍射Key words
Al-LiBH4 composite material/ Microcalorimetry/ Hydrogen generation / Mechanical ball milling/X-Ray diffraction分类
化学化工引用本文复制引用
刘昊,徐芬,孙立贤,曹忠,周怀营..Al-LiBH4复合材料的制备与产氢性能[J].高等学校化学学报,2013,34(8):1953-1958,6.基金项目
国家自然科学基金(批准号:21173111,51071081,51071146,21075011)和国家"九七三"计划项目(批准号:2010CB631303,2012BAD31B08)资助. （批准号:21173111,51071081,51071146,21075011）
