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非离子型聚丙烯酰胺絮凝剂的制备及其絮凝性能

王永军 方申文 郭海军 夏旖旎 李林御

化工环保2013,Vol.33Issue(4):358-362,5.
化工环保2013,Vol.33Issue(4):358-362,5.

非离子型聚丙烯酰胺絮凝剂的制备及其絮凝性能

Preparation of Nonionic Polyacrylamide Flocculant and Its Flocculation Capability

王永军 1方申文 2郭海军 1夏旖旎 2李林御2

作者信息

  • 1. 中海油能源发展股份有限公司钻采工程研究院,天津300452
  • 2. 西南石油大学化学化工学院,四川成都610500
  • 折叠

摘要

Abstract

Nonionic polyacrylamide (PAM-APAP) flocculant with good flowability was prepared by inverse emulsion polymerization using acrylamide(AM) and AE200 type polymerizable alkylpheol polyether (APAP)as monomers.The factors affecting the polymerization were studied.The optimum preparation conditions are as follows:total monomer mass fraction 35%,m(AM) ∶ m(APAP)=9.0 ∶ 1.0,mixed emulsifier Tween 80+Span 80 dosage 7% of the total mass of oil and water,m(Span80) ∶ m(Tween80)=7.0 ∶ 1.5,V50 dosage 1.5‰ of the total monomer mass,reaction temperature 50℃.Comparing with other flocculants,PAM-APAP has better flocculation effect with less dosage.When the PAM-APAP dosage is 100 mg/L,the removal rates of turbidity and oil from polymer flooding wastewater are 87.9% and 89.5% respectively,in addition,the floc is not viscous.

关键词

反相乳液聚合/非离子型聚丙烯酰胺/聚合物驱油/絮凝剂/废水处理

Key words

inverse emulsion polymerization/ nonionic polyacrylamide/ polymer flooding/ flocculant/wastewater treatment

分类

化学化工

引用本文复制引用

王永军,方申文,郭海军,夏旖旎,李林御..非离子型聚丙烯酰胺絮凝剂的制备及其絮凝性能[J].化工环保,2013,33(4):358-362,5.

基金项目

国家科技重大专项子课题"渤海油田聚合物驱采出液污水处理技术研究" (2011ZX05057-004-02). (2011ZX05057-004-02)

化工环保

OA北大核心CSCDCSTPCD

1006-1878

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