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磷酸活化稻秆制备中孔活性炭的研究

卢辛成 蒋剑春 孙康 谢新苹 王金表

林产化学与工业2013,Vol.33Issue(4):43-47,5.
林产化学与工业2013,Vol.33Issue(4):43-47,5.DOI:10.3969/j.issn.0253-2417.2013.04.008

磷酸活化稻秆制备中孔活性炭的研究

Preparation of Mesoporous Activated Carbon from Rice Straw Using Phosphoric Acid

卢辛成 1蒋剑春 2孙康 3谢新苹 4王金表1

作者信息

  • 1. 中国林业科学研究院林产化学工业研究所
  • 2. 生物质化学利用国家工程实验室
  • 3. 国家林业局林产化学工程重点开放性实验室
  • 4. 江苏省生物质能源与材料重点实验室,江苏南京210042
  • 折叠

摘要

Abstract

Mesoperous activated carbon was prepared from rice straw by chemical activation with phosphoric acid and characterized by N2 adsorption,elemental analysis and scanning electron micrograph.The results showed that activated carbon was pre-ac-tivated at 140 ℃ for about 60 min and then prepared at the impregnated ratio 3:1 (mass ratio),activation temperature 450 ℃,activation duration 60 min.Under this condition,characteristics of activated carbon are:the yeild 25%,methylene blue adsorption value 215 mg/g,iodine adsorption values 835 mg/g,decolorization of caramel (A) 110%,ash content 3.03%,pecific surface area 967.7 m2/g,total volume 1.12 cm3/g,average pore diameter 4.6 rim.The ration of mesopores of activated carbon made from rice straw is 84.8 %.Rice straw can be used as the material to prepare activated carbon with mesoperes.

关键词

稻秆/中孔活性炭/制备/化学法/表征

Key words

rice straw/ mesoperous activated carbon/ preparation/ chemical activation/ characterization

分类

化学化工

引用本文复制引用

卢辛成,蒋剑春,孙康,谢新苹,王金表..磷酸活化稻秆制备中孔活性炭的研究[J].林产化学与工业,2013,33(4):43-47,5.

基金项目

中国林科院林业新技术所基本科研业务费专项资金(CAFINT2013C02) (CAFINT2013C02)

江苏省自然科学基金(BK2012514) (BK2012514)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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