天津工业大学学报2013，Vol.32Issue(4)：14-18,5.
聚吡咯/腈氯纶复合纳米纤维的制备及其导电性能
Fabrication and conductive properties of polypyrrole/AN-VDC copolymer composite nanofibers
摘要
Abstract
Polypyrrole (PPy) is synthesized by chemical oxidation method in the presence of toluene sulfonate (TSNa),dodecyl sulfonic acid sodium salt (DSNa),dodecyl-benzene sulfonic acid sodium salt (DBSNa) and di-(2-ethylhexyl) sulfosuccinate sodium salt (DEHS),and then PPy is mixed with AN-VDC copolymer [P (AN-coVDC)] solution.PPy/P (AN-co-VDC) composite nanofibers are prepared via electrospinning.The thermal stability and conductivity properties are investigated using scanning electron microscopy (SEM),thermal gravimetric analysis(TGA) and four-probe tester.The results show that dopants have a great influence on morphology,thermal stability and conductivity properties of PPy.The thermal stability of composite nanofibers is much higher than PPy powders and P(AN-co-VDC) nanofibers with the same dopant.The conductivity of DEHS doped PPy/P (AN-coVDC) nanofibers is the maximum among all nanofibers,which reaches to (20.91 ±4.60) S/cm.关键词
聚吡咯/腈氯纶/静电纺丝/纳米纤维/掺杂/电导率Key words
polypyrrole/ P(AN-co-VDC)/ electrospinning/ nanofiber/ dope/ conductivity分类
化学化工引用本文复制引用
赵磊,周斌,王宁,李春蕾,张兴祥..聚吡咯/腈氯纶复合纳米纤维的制备及其导电性能[J].天津工业大学学报,2013,32(4):14-18,5.基金项目
天津市教育委员会基金资助项目(SB20080018) （SB20080018）
天津工业大学研究生科技创新项目(12109) （12109）
