新型炭材料2013，Vol.28Issue(4)：254-261,8.DOI:10.1016/S1872-5805(13)60079-7
表面活性剂改性的大孔径介孔炭对电极染料敏化太阳电池
An efficient dye-sensitized solar cell using surfactant-modified mesoporous carbon film as a counter electrode
摘要
Abstract
Mesoporous carbon (MC),prepared by the carbonization of phenol resin using ethylene glycol as a pore forming agent,was used as the catalyst of the counter electrode in dye-sensitized solar cells (DSCs) fabricated by a paste coating method at low temperature,where a non-ionic surfactant,Triton X100,was used as a modifier of the paste.Fractal dimensions (DF) were used to evaluate the morphological difference of the MC films on the substrate with surfactant content.The efficiency of the DSCs using the MC modified by the surfactant reaches a maximum of 5.65％ for 0.6g MC with 0.1 mL surfactant.This is 46.5％ higher than that of DSCs using activated carbon as a catalyst in the counter electrode,and 95.4％ of the value obtained using DSCs with a Pt counter electrode under the same conditions.The performance improvement of the surfactant-modified MC counter electrode is attributed to a uniform MC film with a low DF value induced by adding the surfactant,a large average mesopore size of 34.6 nm that is favorable for mass transport,and a high-surface-area glassy carbon structure that has a high content of active sites.关键词
介孔炭/染料敏化太阳电池/对电极/表面活性剂/低温制备Key words
Dye-sensitized solar cells/ Counter electrode/Mesoporous carbon/ Surfactant/ Low temperature分类
信息技术与安全科学引用本文复制引用
徐顺建,罗玉峰,钟炜,肖宗湖..表面活性剂改性的大孔径介孔炭对电极染料敏化太阳电池[J].新型炭材料,2013,28(4):254-261,8.基金项目
国家自然科学基金(51162025 （）
51164033) （）
江西省自然科学基金(2010GQC0178) （2010GQC0178）
西安交通大学金属材料强度国家重点实验室开放研究项目(20111207).National Natural Science Foundation of China (51162025 （20111207）
51164033),Natural Science Foundation of Jiangxi (2010GQC0178) （2010GQC0178）
State Key Laboratory for Mechanical Behavior of Materials (20111207). （20111207）
