北京科技大学学报Issue(12)：1569-1579,11.
基于离子和分子共存理论的炉渣氧化能力表征
Expression of oxidation ability for metallurgical slags based on the ion and molecule coexistence theory
摘要
Abstract
The defined oxidation ability of metallurgical slag based on the ion and molecule coexistence theory (IMCT), i.e., the comprehensive mass action concentration of iron oxides NFetO, was verified by comparing the calculated NFet O and the reported activity of iron oxides aFet O in selected 14 slag systems. To calculate NFet O in the selected slag systems, a thermodynamic model for calculating the mass action concentrations of structural units in CaO-SiO2-MgO-FeO-Fe2O3-MnO-Al2O3-P2O5 type slag systems, i.e., the IMCT-Ni thermodynamic model was developed. NFetO in the other 13 slag systems can be obtained by simplifing this IMCT-Ni. It is shown that the defined comprehensive mass action concentration of iron oxides NFet O is more accurate than the measured activity of iron oxides aFet O in characterizing the oxidation ability of the selected Fet O-containing slag systems.关键词
铁氧化物/质量作用浓度/活度系数/共存理论/结构单元Key words
iron oxides/mass action concentration/activity coeffcients/coexistence theory/structural units分类
冶金工业引用本文复制引用
李鹏程,李晋岩,张盟,张建良,张鉴,杨学民..基于离子和分子共存理论的炉渣氧化能力表征[J].北京科技大学学报,2013,(12):1569-1579,11.基金项目
国家自然科学基金资助项目(51174186) （51174186）
