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纳米HMX的制备及热性能分析和感度研究

曾江保 刘杰 王龙祥 刘巧娥 李青 王毅 姜炜 李凤生

爆破器材Issue(1):8-12,5.
爆破器材Issue(1):8-12,5.DOI:10.3969/j.issn.1001-8352.2014.01.002

纳米HMX的制备及热性能分析和感度研究

Preparation,Thermal Performance Analysis and Sensitivities Study of Nano HMX

曾江保 1刘杰 1王龙祥 1刘巧娥 1李青 1王毅 1姜炜 1李凤生1

作者信息

  • 1. 南京理工大学国家特种超细粉体工程技术研究中心 江苏南京,210094
  • 折叠

摘要

Abstract

Nano HMX was prepared by the ball milling method .The particle size distribution was analyzed by a laser particle size analyzer .At the same time ,the particle size and the morphology of nano HMX were character-ized through SEM .The thermal decomposition features and thermal stability of nano HMX were examined by a TG/DSC .Furthermore ,the explosion temperature in five seconds and the sensitivities of nano HMX were also tested .It was found that most of the particles were below 100 nm .The maximum weight loss temperature ,the apparent acti-vation energy Ea ,the self-ignition temperature and the explosion temperature in five seconds were lower than those of raw HMX by 3 4.6℃ ,11 1.9 kJ/mol ,2 1.1K and 4 9.℃ respectively .The electrostatic sensitivity and the sensitivity to flame of nano HMX were the same as raw HMX .The friction ,impact and shock sensitivities of nano HMX were decreased by 28% ,20 2.% and 56 4.% ,respec-tively .

关键词

纳米/HMX/制备/机械球磨/热性能/感度

Key words

Nano HMX/Preparation/Ball milling/Thermal properties/Sensitivities

分类

军事科技

引用本文复制引用

曾江保,刘杰,王龙祥,刘巧娥,李青,王毅,姜炜,李凤生..纳米HMX的制备及热性能分析和感度研究[J].爆破器材,2014,(1):8-12,5.

基金项目

国家自然科学基金(51206081);中央高校基本科研业务费专项 ()

爆破器材

OACSTPCD

1001-8352

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