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过渡金属氧化物用作锂空气电池催化剂

任现平 刘桂成 徐国峰 李建玲

电池Issue(1):6-8,3.
电池Issue(1):6-8,3.

过渡金属氧化物用作锂空气电池催化剂

Using transition metal oxide as catalyst of lithium-air battery

任现平 1刘桂成 2徐国峰 1李建玲2

作者信息

  • 1. 北京科技大学钢铁冶金新技术国家重点实验室,北京 100083
  • 2. 北京科技大学物理化学系,北京 100083
  • 折叠

摘要

Abstract

The catalytic performance of 4 kinds of transition metal oxides such as MnO2 ,V2 O5 ,Sb2 O3 and CeO2 used as catalyst of lithium-air battery was compared;effect of crystal type of MnO2 to the performance of lithium-air battery was studied. Porous nano-spheres birnessite-type manganese dioxide(Bir-MnO2 )had the best catalytic performance. While the mass ratio of Bir-MnO2 ,Super P graphite and poly(vinylidene fluoride)in the electrode was 1∶3∶1 ,when cycled in 2.0~4.5 V with the current density of 0.05 mA/cm2 ,the specific discharge capacity of the prepared lithium-air battery could reach to 832.60 mAh/g,the capacity retention rate was higher than 52% in the 5th cycle.

关键词

锂空气电池/过渡金属氧化物/二氧化锰(MnO2)/催化性能

Key words

lithium-air battery/transition metal oxide/manganese dioxide(MnO2)/catalytic performance

分类

信息技术与安全科学

引用本文复制引用

任现平,刘桂成,徐国峰,李建玲..过渡金属氧化物用作锂空气电池催化剂[J].电池,2014,(1):6-8,3.

基金项目

国家863项目(2012AA110302),新世纪优秀人才支持计划 ()

电池

OA北大核心CSCDCSTPCD

1001-1579

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