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混合铁源制备碳包覆磷酸铁锂

王伟 赵领 张峥 刘兴泉

电池Issue(1):24-27,4.
电池Issue(1):24-27,4.

混合铁源制备碳包覆磷酸铁锂

Preparing carbon coated lithium ferrous phosphate using mixed iron sources

王伟 1赵领 1张峥 1刘兴泉1

作者信息

  • 1. 电子科技大学微电子与固体电子学院,四川 成都 610054
  • 折叠

摘要

Abstract

Carbon coated lithium ferrous phosphate(LiFePO4/C)as cathode material of Li-ion battery was synthesized by solid state reaction method using mix iron sources. The surface morphology,crystal structure and the electrochemical performance were charac-terized by SEM,XRD,charge-discharge testing and electrochemical impedance spectra(EIS). The composite synthesized at 700 ℃with mixed iron sources n(FeC2 O4·2H2 O)∶n(FePO4 )=1∶1 had better electrochemical performance,when charged-discharged in 2.5 ~4.1 V,the 0.2 C specific discharge capacity was 165.9 mAh/g,the specific discharge capacity in the initial and 20th cycle at 2.0 C was 135.3 mAh/g and 141.9 mAh/g,respectively.

关键词

磷酸铁锂(LiFePO4)/正极材料/混合铁源/碳包覆

Key words

lithium ferrous phosphate(LiFePO4 )/cathode material/mixed iron sources/carbon coating

分类

信息技术与安全科学

引用本文复制引用

王伟,赵领,张峥,刘兴泉..混合铁源制备碳包覆磷酸铁锂[J].电池,2014,(1):24-27,4.

基金项目

国家自然科学基金(21071026),电子科技大学杰出人才引进项目 ()

电池

OA北大核心CSCDCSTPCD

1001-1579

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