大连理工大学学报Issue(1)：13-19,7.DOI:10.7511/dllgxb201401003
CuO／ZnO／CeO2／ZrO2催化剂上甲醇水蒸气重整制氢反应机理研究
Research on mechanism of methanol steam reforming for hydrogen-making over CuO/ZnO/CeO2/ZrO2 catalyst
摘要
Abstract
The mechanism of methanol steam reforming for hydrogen-making over CuO/ZnO/CeO2/ZrO2 is investigated by in situ FT-IR .The experimental results show that methanol steam reforming for hydrogen-making consists of methanol dehydrogenation ,methyl formate hydrolysis and reverse water gas shift (RWGS) .The by-product CO formation is mainly due to the RWGS reaction ,which is the reason that the CO level in the reforming gas is below the equilibrium concentration .关键词
甲醇水蒸气重整/甲醇吸附/氢气/一氧化碳/二氧化碳Key words
methanol steam reforming/methanol adsorption/hydrogen/carbon monoxide/carbon dioxide分类
化学化工引用本文复制引用
张磊,潘立卫,倪长军,彭家喜,赵生生,王树东,胡永康,王安杰..CuO／ZnO／CeO2／ZrO2催化剂上甲醇水蒸气重整制氢反应机理研究[J].大连理工大学学报,2014,(1):13-19,7.基金项目
国家自然科学基金资助项目（21076206）；“九七三”国家重点基础研究发展计划资助项目（2010CB732302）；“八六三”国家高技术研究发展计划资助项目（2011AA050706）． （）
