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三元复合驱硅垢防垢剂SY-KD的合成及应用

程杰成 王庆国 周万富 李苏 程铁欣 周广栋

高等学校化学学报Issue(2):332-337,6.
高等学校化学学报Issue(2):332-337,6.DOI:10.7503/cjcu20130894

三元复合驱硅垢防垢剂SY-KD的合成及应用

Synthesis and Application of Silicon Scale Inhibitor SY-KD Under the ASP Flooding System

程杰成 1王庆国 1周万富 1李苏 2程铁欣 2周广栋2

作者信息

  • 1. 大庆油田有限责任公司,大庆163453
  • 2. 吉林大学化学学院,长春130012
  • 折叠

摘要

Abstract

By analyzing silica scale formation mechanism under the alkaline/surfactant/polymer( ASP) floo-ding system, we designed and synthesized a new type of scale inhibitor SY-KD. SY-KD inhibitor is a complex mixture that made by the polymer( CAABS) which is copolymerized by acrylic acid( AA) and p-methyl allyl oxybenzene sulfonate(MBS) &2-phosphate-1,2,4-tricarboxylic acid(PBTC). The carboxyl functional groups of SY-KD can link to the orthosilicic acid molecules or its dimer acid through hydrogen bonding interactions, since the molecular chain of SY-KD's steric effect would prevent further polymerization that the orthosilicic acid molecules or its dimer acid form silica dioxide. Laboratory experiments studies have shown that SY-KD is a good inhibitor for ASP flooding, each component of SY-KD can achieve the silicon scale inhibition ability mainly through the polymerization inhibition, the adsorption and dispersion, and the dissolution of insoluble SiO2 . Field tests have shown that SY-KD scale inhibitor delays the average pump detection period of scaled wells from about 50 d to 300 d.

关键词

三元复合驱/硅垢/防垢剂

Key words

Alkaline/surfactant/polymer( ASP)/Silicon scale/Scale inhibitor

分类

化学化工

引用本文复制引用

程杰成,王庆国,周万富,李苏,程铁欣,周广栋..三元复合驱硅垢防垢剂SY-KD的合成及应用[J].高等学校化学学报,2014,(2):332-337,6.

基金项目

大庆油田有限责任公司项目(批准号:DQYT-1204003-2012-JS-1165,2011-JS-471,2009-JS-1469,2008-JS-820)资助.@@@@Supported by the Daqing Oilfield Co., Ltd., China(Nos. DQYT-1204003-2012-JS-1165,2011-JS-471,2009-JS-1469,2008-JS-820) (批准号:DQYT-1204003-2012-JS-1165,2011-JS-471,2009-JS-1469,2008-JS-820)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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