开放骨架磷酸铁的合成与性质OA北大核心CSCDCSTPCD
Synthesis and Characterization of a New Open-framework Iron Phosphate
通过使用二丙烯基三胺为结构导向剂,在水热体系中合成出一例具有新型三维开放骨架结构的磷酸铁化合物JU94(2H3O [Fe2P2O8(OH)2]).单晶X射线衍射分析结果显示,该化合物结晶在单斜晶系P21/c空间群,晶胞参数a=0.97566(5) nm, b=0.98560(5) nm, c=1.24514(5) nm,β=129.651(3)º, V=0.92189(8) nm3.该化合物的骨架结构是由FeO6八面体和PO4四面体连接构成,以四…查看全部>>
Synthesis of novel iron phosphates has gained much attention due to their structure diversity and unique magnetic property. In this work, a new iron phosphate JU94( 2H3O [Fe2P2O8(OH)2]) with novel three-dimensional open framework has been hydrothermally synthesized using dipropylenetriamine as the structure-directing agent( SDA) . Its structure was determined by single-crystal X-ray diffraction. It crystallizes in monoclinics pace group, P21/c, with a=0.9756…查看全部>>
王艳艳;张铮;孙延俊;李激扬
吉林大学化学学院，无机合成与制备化学国家重点实验室，长春130012Chemical Reaction Engineering Group，Institute of Technology and Management，University of Groningen，Groningen 9747AG，The Netherlands吉林大学化学学院，无机合成与制备化学国家重点实验室，长春130012吉林大学化学学院，无机合成与制备化学国家重点实验室，长春130012
化学化工
磷酸铁开放骨架水热合成反铁磁性
Iron phosphateOpen-frameworkHydrothermal synthesisAnti-ferromagnetic property
《高等学校化学学报》 2014 (3)
新型杂原子磷酸铝分子筛的合成与催化性能研究
449-454,6
国家自然科学基金(批准号:21271081)和国家“九七三”计划项目(批准号:2011CB808703)资助.@@@@ Supported by the National Natural Science Foundation of China ( No.21271081) and the State Basic Research Project of China ( No.2011CB808703)
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