高等学校化学学报Issue(4)：665-688,24.DOI:10.7503/cjcu20131066
原子团簇上一氧化碳的氧化
Oxidation of Carbon Monoxide on Atomic Clusters
摘要
Abstract
Carbon monoxide binds to hemoglobin much more tightly than does molecular oxygen, so CO is highly tox-ic to humans and animals. Oxidation of CO into CO2 is a major solution to removal of carbon monoxide in air purifica-tion. CO is also a simple molecule and CO oxidation serves as a prototypical reaction for heterogeneous processes. Atomic clusters composed of limited numbers of atoms are experimentally and theoretically tractable models for hetero-geneous catalysis. During the last decade, a number of publications have been devoted to understanding the CO oxi-dation at a molecular level based on the investigations of gas phase atomic clusters under controlled and well reproduc-ible conditions. In this review, we will go through the reported CO oxidations by gas phase atomic clusters. Advanta-ges, new insights, and problems to be solved involved with the cluster approach for the title reaction will be summa-rized.关键词
一氧化碳氧化/催化/原子团簇/质谱/密度泛函理论计算Key words
CO oxidation/Catalysis/Atomic cluster/Mass spectrometry/Density functional theory computation分类
化学化工引用本文复制引用
刘清宇,何圣贵..原子团簇上一氧化碳的氧化[J].高等学校化学学报,2014,(4):665-688,24.基金项目
国家自然科学基金(批准号:20933008,21325314)、国家重点基础研究发展计划(批准号:2013CB834603,2011CB932302)和中国科学院化学研究所前沿交叉重点项目(批准号：CMS-PY-201306)资助.@@@@Supported by the National Natural Science Foundation of China ( Nos.20933008 and 21325314), Major Research Plan of China ( Nos.2013CB834603 and 2011CB932302), and Institute of Chemistry, Chinese Academy of Sciences(No. CMS-PY-201306) （批准号:20933008,21325314）
