高校化学工程学报Issue(6)：919-924,6.DOI:10.3969/j.issn.1003-9015.2013.06.001
有机化合物液体等压热容的关联和预测
Correlation and Prediction of Liquid Constant Pressure Heat Capacities for Organic Compound
王双成1
作者信息
- 1. 河南广播电视大学 理工学院，河南 郑州 450008
- 折叠
摘要
Abstract
According to the definition of liquid constant pressure heat capacity and the Rackett equation, a new correlation model for liquid constant pressure heat capacities of organic compound was proposed in this paper. From the proposed model, heat capacities of 46 kinds of liquid organic compounds with 318 data points at different temperatures were predicted. The comparison with the literature data shows that the calculation results are satisfactory with the overall average relative deviations of 3.92%, so the proposed correlation is more accurate than literature correlations. The proposed model is applicable to predict the liquid constant pressure heat capacities of every organic compound at different temperatures. The proposed model is simple and convenient. By using the easy ferreted out physical properties of mole mass, critical temperature, critical pressure,normal boiling point, normal melting point, critical compress factor and eccentric factor, the liquid constant pressure heat capacities of the organic compound at different temperatures can be directly predicted without the need of the constant pressure heat capacity data of corresponding ideal gas.关键词
有机化合物/液体/等压热容/关联/预测Key words
organic compound/liquid/constant pressure heat capacity/correlation/prediction分类
化学化工引用本文复制引用
王双成..有机化合物液体等压热容的关联和预测[J].高校化学工程学报,2013,(6):919-924,6.
