化工进展Issue(11)：2614-2620,7.DOI:10.3969/j.issn.1000-6613.2013.11.015
非光气法催化合成碳酸二苯酯研究进展
Progress in the catalytic synthesis of diphenyl carbonate via non-phosgene routes
摘要
Abstract
This paper is aimed to review the recent progress in catalytic synthesis of diphenyl carbonate (DPC) by four non-phosgene routes,i.e. transesterification,oxidative carbonylation of phenol, transesterification-decarbonylation of dimethyl oxalate and phenolysis of urea. The review mainly focuses on the catalyst,the reaction condition,conversion of the reactant and the yield of product for each non-phosgene route,the advantages and disadvantages of which are described. Two routes, transesterification and phenolysis of urea,are preferred based on the comparison of raw materials, catalyst preparation,technology,and the energy consumption for four routes,so,these two routes may be dominant in future.关键词
碳酸二苯酯/非光气法/催化合成Key words
diphenyl carbonate/non-phosgene route/catalytic synthesis分类
化学化工引用本文复制引用
刘勇,刘坚..非光气法催化合成碳酸二苯酯研究进展[J].化工进展,2013,(11):2614-2620,7.基金项目
江西省高等学校科技落地计划（KJLD12100）及江西省教育厅科技项目（GJJ12653）。 （）
