化工进展Issue(11)：2631-2637,7.DOI:10.3969/j.issn.1000-6613.2013.11.017
氧化羰基化合成碳酸二甲酯催化剂的研究进展
Advances in the catalytic synthesis of dimethyl carbonate by oxidative carbonylation
摘要
Abstract
In past few years,methanol oxidative carbonylation is an important method for the synthesis of dimethyl carbonate (DMC) , becomes one of the most important approaches for clean coal utilization,and has got a significant development. In this paper,according to its supporters,the supported copper-based catalysts are divided to three categories:molecular sieve supporters,activated carbon supporters and other supporters. Their research progress is fully reviewed,including research advances in catalyst for synthesis technology,the feature and microstructure of surface,the catalytic performance and catalysis mechanism. Through in-depth analysis and comparison,it’s concluded that chlorine-free copper-based catalysts with zeolite or actived carbon as supporter are prospective in future,because of its high catalytic activity,high stability and no Cl−in the active component of CuCl/CuCl2 catalysts,which avoid the harmful HCl production in the reaction processes.关键词
铜基催化剂/甲醇/碳酸二甲酯/氧化羰基化Key words
copper-based catalyst/methanol/dimethyl carbonate/oxidative carbonylation分类
化学化工引用本文复制引用
王坤,李忠,李安民..氧化羰基化合成碳酸二甲酯催化剂的研究进展[J].化工进展,2013,(11):2631-2637,7.基金项目
国家自然科学基金项目（21276169）。 （）
