化工进展Issue(1)：16-20,49,6.DOI:10.3969/j.issn.1000-6613.2014.01.003
1-氯-1,1-二氟乙烷裂解制备偏氟乙烯的研究进展
Research progress in the pyrolysis of 1-chloro-1,1-difluoroethane to vinylidene fluoride
郑海峰 1尹红 1袁慎峰 1陈志荣 1刘乘风2
作者信息
- 1. 浙江大学化学工程与生物工程学系，浙江 杭州310027
- 2. 临海市利民化工有限公司，浙江 临海 317021
- 折叠
摘要
Abstract
Vinylidene fluoride is one of the most important monomers in fluorine industry,which is mainly prepared by the pyrolysis of 1-chloro-1,1-difluoroethane (HCFC-142b) at high temperature. This research progress in the pyrolysis mechanism of HCFC-142b to vinylidene fluoride was introduced. The technologies and the development trend of catalytic pyrolysis of HCFC-142b were reviewed together with the improvements in the structure of cracking tube. In addition,study on the rectification of vinylidene fluoride was discussed. It is proposed that in-depth study on the mechanism of the pyrolysis of HCFC-142b and the effects of the material and structure of cracking tube should be conducted. Learning from the research progress in the pyrolysis of hydrocarbons,the difficulty of high energy consumption,catalyst loss,coking and other problems faced in the pyrolysis of HCFC-142b will be solved.关键词
1-氯-1,1-二氟乙烷/偏氟乙烯/反应机理/裂解技术/精馏Key words
1-chloro-1,1-difluoroethane/vinylidene fluoride/mechanism/pyrolysis technology/rectification分类
化学化工引用本文复制引用
郑海峰,尹红,袁慎峰,陈志荣,刘乘风..1-氯-1,1-二氟乙烷裂解制备偏氟乙烯的研究进展[J].化工进展,2014,(1):16-20,49,6.
