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二氧化钛/氧化石墨烯复合光催化剂的合成

董如林 莫剑臣 张汉平 姜苏 陈智栋 金长春

化工进展Issue(3):679-684,6.
化工进展Issue(3):679-684,6.DOI:10.3969/j.issn.1000-6613.2014.03.027

二氧化钛/氧化石墨烯复合光催化剂的合成

Synthesis of the titania/graphene oxide composite photocatalyst

董如林 1莫剑臣 1张汉平 1姜苏 1陈智栋 1金长春1

作者信息

  • 1. 常州大学石油化工学院,江苏 常州 213164
  • 折叠

摘要

Abstract

A series of titania/graphene oxide (TiO2/GO) composite photocatalysts with different mass fractions of graphene oxide were prepared in an aqueous system by hydrothermal method,using tetrabutyl titanate and graphene oxide as starting raw materials. FE-SEM results show that the TBOT is adsorbed on graphene oxide surface in multimolecular layer,and finally transformed into anatase TiO2 during hydrothermal process. When the mass fraction of graphene oxide is below 3%,the product photocatalyst consists of pure TiO2 and TiO2/GO composite. As the graphene oxide content exceeds 5%,the product consists of only TiO2/GO composite. The results of electrochemical measurement indicate that the carrier transport efficiency in TiO2 electrode increases after TiO2 is combined with GO. As the mass fraction of graphene oxide reaches 10%,the composite photocatalyst shows the highest photocatalytic activity for methylene. The photocatalytic activity can be further greatly enhanced after the bound graphene oxide is reduced to graphene.

关键词

水热/TiO2/GO复合光催化剂/氧化石墨烯/电化学/催化剂/活性

Key words

hydrothermal/TiO2/GO composite photocatalyst/graphene oxide/electrochemistry/catalyst/activation

分类

化学化工

引用本文复制引用

董如林,莫剑臣,张汉平,姜苏,陈智栋,金长春..二氧化钛/氧化石墨烯复合光催化剂的合成[J].化工进展,2014,(3):679-684,6.

基金项目

国家自然科学基金项目(51273027)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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