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纳米二氧化铈的制备及光催化性能

耿九光 臧文杰 李毅 陶建强

化工进展Issue(3):720-723,4.
化工进展Issue(3):720-723,4.DOI:10.3969/j.issn.1000-6613.2014.03.034

纳米二氧化铈的制备及光催化性能

Preparation and photocatalytic performance of nano-ceria

耿九光 1臧文杰 1李毅 1陶建强1

作者信息

  • 1. 长安大学材料科学与工程学院,陕西 西安 710064
  • 折叠

摘要

Abstract

A facile route for the synthesis of nano cerium oxide powder (CeO2) is provided by the oxidation of cerium nitrate [Ce(NO3)3] with hydrogen peroxide and precipitation with ammonia. Factors influencing the size and morphology of the particle are analyzed. And the product is observed with a scanning electron microscope (SEM). Exhaust degradation test device is designed to study the photocatalytic properties of nano-CeO2 in the degradation of harmful gases within the automobile exhaust (HC and NOx). The results indicate that the ammonia concentration is 1.0 mol/L,with ethanol and ethylene glycol as dispersant,when the Ce(NO3)3 concentration is 2.0 mol/L,and the as-prepared nano-CeO2 is sphere-like nanoparticle aggregates with diameters around 50 nm and of good dispersibility,with which the degradation of HC and NOx amounts of 11% and 90% respectively, showing a good photocatalytic performance.

关键词

纳米材料/二氧化铈/氧化-沉淀法/光催化/尾气降解

Key words

nanomaterial/ceria/oxidation-precipitation method/photocatalysis/exhaust degradation

分类

化学化工

引用本文复制引用

耿九光,臧文杰,李毅,陶建强..纳米二氧化铈的制备及光催化性能[J].化工进展,2014,(3):720-723,4.

基金项目

国家自然科学基金项目(51108374)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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