化工进展Issue(5)：1164-1169,6.DOI:10.3969/j.issn.1000-6613.2014.05.015
基于高磁场固态碳13核磁共振法对甘肃油页岩生油潜力的研究
Gansu oil shale generation potential based on solid-state 13C NMR with high magnetic field
摘要
Abstract
A series of solid-state 13C NMR experiments for Gansu oil shale were conducted with the BRUKER AVANCE III 400 WB spectrometer analyzer. By using cross-polarization magic angle spinning (CP/MAS) technology and total sideband suppression (TOSS),a high-resolution spectrogram was obtained. Analyzing the relationship between generation potential and total organic carbon, aliphatic carbon,potential carbon showed that potential carbon was the primary factor in determining generation potential. Comparing the data of dry distillation experiment and solid-state 13C NMR indicated that the carbon of toal organic carbon transformed to oil in the experiment was related to potential carbon. Theoretical analysis of tansformation of organic carbon into oil agreed with dry distillation experiment.关键词
油页岩/核磁共振/脂肪族碳/油潜力碳/生油潜力Key words
oil shale/nuclear magnetic resonance/aliphatic carbon/potential carbon/generation potential分类
能源科技引用本文复制引用
王擎,朱玉成,贾春霞,闫宇赫..基于高磁场固态碳13核磁共振法对甘肃油页岩生油潜力的研究[J].化工进展,2014,(5):1164-1169,6.基金项目
国家自然科学基金（51276034）及长江学者和创新团队发展计划（IRT13052）项目。 （）
