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循环流化床锅炉飞灰增湿低温悬浮脱硫特性

王勤辉 蔡毅 程乐鸣 许霖杰 方梦祥

化工学报Issue(2):684-691,8.
化工学报Issue(2):684-691,8.DOI:10.3969/j.issn.0438-1157.2014.02.045

循环流化床锅炉飞灰增湿低温悬浮脱硫特性

Suspended fluidized bed desulfurization characteristics of humidified fly ashes from circulating fluidized bed at low temperature

王勤辉 1蔡毅 1程乐鸣 1许霖杰 1方梦祥1

作者信息

  • 1. 浙江大学能源清洁利用国家重点实验室,浙江 杭州 310027
  • 折叠

摘要

Abstract

Humidified activation of fly ashes from circulating fluidized bed (CFB) boilers was conducted. Samples of the fly ash were characterized by desulfurization in the suspended fluidized bed and scanning electron microscopy (SEM). The desulfurization of humidified fly ashes was conducted at low temperature. The results indicated that with increase of reaction temperature, the calcium utilization increased when water/CaO ratio was 1. The utilization increased continuously and then decreased with temperature when the ratio was 3 or 5. The rate decreased when the ratio was 10. It was shown that the calcium utilization of humidified fly ashes in a suspended fluidized bed could be increased from 41%to 60%. The optimal reaction temperature was between 60℃ and 80℃. The results from SEM showed that treatment of humidified activation promoted an increase in ash porosity, while the porosity contributed to further desulfurization in suspended fluidized beds.

关键词

脱硫/飞灰/低温/增湿/活化/循环流化床

Key words

desulfurization/fly ash/low temperature/humidification/activation/circulating fluidized bed

分类

化学化工

引用本文复制引用

王勤辉,蔡毅,程乐鸣,许霖杰,方梦祥..循环流化床锅炉飞灰增湿低温悬浮脱硫特性[J].化工学报,2014,(2):684-691,8.

基金项目

国家“十二五”科技支撑计划项目(2012BAA02B01-03)。@@@@supported by the National Key Technology Research and Development Program (2012BAA02B01-03) (2012BAA02B01-03)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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