化工学报Issue(3)：1111-1117,7.DOI:10.3969/j.issn.0438-1157.2014.03.048
ATRP法均相制备纤维素/甲基丙烯酸丁酯接枝聚合物
Preparation of cellulose graft poly(butyl methacrylate) copolymers by homogeneous ATRP
摘要
Abstract
Cellulose graft poly(butyl methacrylate) copolymers (Cellulose-g-PBMA) were prepared by homogeneous atom transfer radical polymerization (ATRP) process. Cellulose chloroacetate(Cellulose-ClAc), as macroinitiator, was synthesized first by direct acylation of cotton pulp cellulose with chloroacetyl chloride (ClC2OCl) in cellulose/LiCl/DMAc solution. Thereafter, Cellulose-ClAc was used for the ATRP of BMA (butyl methacrylate) mediated by the FeCl2/four-dimethyl aminopyridine (DMAP) catalytic system. Acylation reaction and grafting polymerization conditions, such as reaction time, reaction temperature and ratio of reactants were investigated. The hydrophobicity of Cellulose-g-PBMA copolymer was studied with contact angle measurements. Cellulose-ClAc and Cellulose-g-PBMA were characterized by means of FTIR,NMR,SEM,TEM, AFM. Gel permeation chromatography (GPC) was used to analyze the characteristics of the activity of polymerization.关键词
纤维素/甲基丙烯酸丁酯/均相ATRP/接枝聚合/疏水性能Key words
cellulose/butyl methacrylate/homogeneous ATRP/graft copolymerization/hydrophobicity分类
化学化工引用本文复制引用
哈丽丹·买买提,开比努尔·艾尔肯,米娜瓦尔·乌买尔..ATRP法均相制备纤维素/甲基丙烯酸丁酯接枝聚合物[J].化工学报,2014,(3):1111-1117,7.基金项目
国家自然科学基金项目（21064008）。@@@@supported by the National Natural Science Foundation of China(21064008) （21064008）
